Synthesis of Substituted Naphthalenes via a Catalytic Ring-Expansion Rearrangement

被引：53

作者：

Glass, Adam C. ^{[1
]}

Morris, Benjamin B. ^{[1
]}

Zakharov, Lev N. ^{[1
]}

Liu, Shih-Yuan ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 21期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ol8019617

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new methodology for the preparation of substituted naphthalenes starting from readily available indenones, organometal reagents, and trimethylsilyldiazomethane via a catalytic rearrangement process is described. Hindered biaryl naphthalenes, including triortho-substituted biaryls, can be accessed through our method. Our results are consistent with a mechanism involving a benzobenzvalene intermediate.

引用

页码：4855 / 4857

页数：3

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