Spectral studies of Fe(III) complexes of dipodal tridentate chelating agents

被引：8

作者：

Siddiqi, Zafar Ahmad ^{[1
]}

Kumar, Sarvendra ^{[1
]}

Khalid, M. ^{[1
]}

Shahid, M. ^{[1
]}

机构：

[1] Aligarh Muslim Univ, Dept Chem, Aligarh 202002, Uttar Pradesh, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2009年 / 71卷 / 05期

关键词：

Fe(III) complexes; Mossbauer spectra; Dipodal tridentate ligand; Magnetic moment; Electronic ligand field spectra; COPPER(II) COMPLEXES; N2S2; COORDINATION; TRIPODAL LIGAND; METAL-COMPLEXES; MACROCYCLE; CLUSTER; ZN; CD;

D O I：

10.1016/j.saa.2008.07.016

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The dipodal ligands (lm) and (Blm) as well as complexes [FeLCl3] [L=lm (1) and Blm (2)] have been prepared and studied using spectroscopic techniques. The magnetic moment, IR. electronic (ligand field), FAB-mass and NMR spectral data indicate a hexa-coordinate geometry around high-spin state Fe3+ where the ligands coordinate as a tridentate [N,N,N] chelating agent. Fe-57-Mossbauer spectral data confirmed the presence of a ligand asymmetry around Fe3+ in a high-spin state electronic configuration (t(2g)(3),e(g)(2), S= 5/2) with nuclear transition Fe(+/- 3/2 -> +/- 1/2) exhibiting Kramer's double degeneracy. The molecular computations provided the optimum energy perspective plots for the molecular geometries giving the important structural data. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.

引用

页码：1845 / 1850

页数：6

共 50 条

[21] The influence of chelating agents upon the dissimilatory reduction of Fe(III) by Shewanella putrefaciens .2. Oxo- and hydroxo-bridged polynuclear Fe(III) complexes
Dobbin, PS
Burmeister, LMR
Heath, SL
Powell, AK
McEwan, AG
Richardson, DJ
BIOMETALS, 1996, 9 (03) : 291 - 301
[22] Influence of Chelating Agents on Biogenic Uraninite Reoxidation by Fe(III) (Hydr)oxides
Stewart, Brandy D.
Girardot, Crystal
Spycher, Nicolas
Sani, Rajesh K.
Peyton, Brent M.
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013, 47 (01) : 364 - 371
[23] Influence of chelating agents on biogenic uraninite reoxidation by Fe(III) (hydr)oxides
Stewart, Brandy D.
Girardot, Crystal
Peyton, Brent M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
[24] Metal chelating agents III: mass spectral studies on the semicarbazone derivatives of benzoin and 2-hydroxy-1-naphthaldehyde
Akinchan, NT
EUROPEAN JOURNAL OF MASS SPECTROMETRY, 2002, 8 (01) : 21 - 26
[25] Spectral studies on the complexes of Yb(III) and Gd(III) to EHPG
Wang, JL
Yang, BS
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2002, 18 (06) : 577 - 581
[26] THERMAL-BEHAVIOR OF DINITROGEN COMPLEXES OF FE(II) WITH CHELATING-AGENTS
LOPEZALCALA, JM
PUERTA, MC
GONZALEZVILCHEZ, F
THERMOCHIMICA ACTA, 1984, 78 (1-3) : 135 - 140
[27] Spectral and magnetic studies on oxovanadium(IV) and copper(II) complexes with tridentate ligands
Shetti, SN
Murty, ASR
Tembe, GL
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1996, 73 (2-3) : 91 - 96
[28] Spectral and Magnetic Studies on Oxovanadium(IV) and Copper(II) Complexes with Tridentate Ligands
J Ind Chem Soc, 2/3 (91):
[29] DFT studies, spectral and biological activity evaluation of binary and ternary sulfamethazine Fe(III) complexes
Mansour, Ahmed M.
JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (16) : 2680 - 2687
[30] Synthesis, spectral and biological studies of Cr(III), Mn(II) and Fe(II) complexes with diacetylmonoxime
Manikshete, A. H.
Kamble, Vaishali N.
Sarsamkar, S. K.
Doedware, S.
ORIENTAL JOURNAL OF CHEMISTRY, 2010, 26 (02) : 573 - 580

← 1 2 3 4 5 →