Spectral studies of Fe(III) complexes of dipodal tridentate chelating agents

被引：8

作者：

Siddiqi, Zafar Ahmad ^{[1
]}

Kumar, Sarvendra ^{[1
]}

Khalid, M. ^{[1
]}

Shahid, M. ^{[1
]}

机构：

[1] Aligarh Muslim Univ, Dept Chem, Aligarh 202002, Uttar Pradesh, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2009年 / 71卷 / 05期

关键词：

Fe(III) complexes; Mossbauer spectra; Dipodal tridentate ligand; Magnetic moment; Electronic ligand field spectra; COPPER(II) COMPLEXES; N2S2; COORDINATION; TRIPODAL LIGAND; METAL-COMPLEXES; MACROCYCLE; CLUSTER; ZN; CD;

D O I：

10.1016/j.saa.2008.07.016

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The dipodal ligands (lm) and (Blm) as well as complexes [FeLCl3] [L=lm (1) and Blm (2)] have been prepared and studied using spectroscopic techniques. The magnetic moment, IR. electronic (ligand field), FAB-mass and NMR spectral data indicate a hexa-coordinate geometry around high-spin state Fe3+ where the ligands coordinate as a tridentate [N,N,N] chelating agent. Fe-57-Mossbauer spectral data confirmed the presence of a ligand asymmetry around Fe3+ in a high-spin state electronic configuration (t(2g)(3),e(g)(2), S= 5/2) with nuclear transition Fe(+/- 3/2 -> +/- 1/2) exhibiting Kramer's double degeneracy. The molecular computations provided the optimum energy perspective plots for the molecular geometries giving the important structural data. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.

引用

页码：1845 / 1850

页数：6

共 50 条

[1] Synthesis, spectral and electrochemical studies on Fe(III) and Mn(II) complexes with a tridentate ligand carrying pendant benzimidazolyl groups
Nohria, L
Mathur, P
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2004, 43 (03): : 548 - 550
[2] SUBSTITUTED HYDRAZONES AS TRIDENTATE CHELATING AGENTS
HEIT, ML
RYAN, DE
ANALYTICA CHIMICA ACTA, 1965, 32 (05) : 448 - &
[3] Mossbauer Spectral Studies of Some Fe(III)-Ketoanil Complexes
Pathak, Vishal
Bharadwaj, K. K.
Agrawal, Anshu
ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (10) : 7563 - 7566
[4] MOSSBAUER AND OTHER SPECTRAL STUDIES OF FE(III) COMPLEXES OF BENZOTHIAZOLINES
GARG, A
TANDON, JP
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1988, 100 (06): : 463 - 468
[5] DINITROGEN COMPLEXES OF CHROMIUM(III) WITH CHELATING-AGENTS
LOPEZALCALA, JM
PUERTA, MC
GONZALEZVILCHEZ, F
TRANSITION METAL CHEMISTRY, 1985, 10 (07) : 247 - 248
[6] Hydroxypyrones, an intriguing family of chelating agents for Fe(III) and Al(III)
Toso, L.
Nurchi, V. M.
Crisponi, G.
Crespo-Alonso, M.
Lachowicz, J., I
Marques, S. M.
Santos, M. A.
Niclos-Gutierrez, J.
Dominguez-Martin, A.
Gonzaez-Perez, J. M.
Zoroddu, M. A.
Peana, M.
11TH EUROPEAN BIOLOGICAL INORGANIC CHEMISTRY CONFERENCE (EUROBIC 11), 2013, : 53 - 56
[7] Synthesis, Characterization and Spectral Studies of Fe(III) and Cr(III) Schiff Base Complexes with Acetoacetanilidoethylenediamine
Santhi, S.
Namboori, C. G. Radhakrishnan
ORIENTAL JOURNAL OF CHEMISTRY, 2011, 27 (03) : 1203 - 1208
[8] Synthesis, Characterization and Spectral Studies of Fe(III) and Cr(III) Schiff base Complexes with Acetoacetanilidepropylenediamine
Santhi, S.
Harikumar, B.
Namboori, C. G. Radhakrishnan
ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (03) : 1003 - 1006
[9] SYNTHESIS AND INFRARED STUDIES OF METHYLGALLIUM(III) AND GALLIUM(III) COMPLEXES WITH TRIDENTATE LIGANDS
PELLERITO, L
CEFALU, R
RUISI, G
GIUDICE, MTL
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 481 (10): : 218 - 224
[10] SYNTHESIS AND REACTIVITIES OF BINUCLEAR IRON(III) COMPLEXES WITH LIGANDS COMPOSED OF 2 TRIDENTATE CHELATING GROUPS
NISHIDA, Y
TAKEUCHI, M
SHIMO, H
KIDA, S
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 96 (01): : 115 - 119

← 1 2 3 4 5 →