Protodecarboxylation of benzoic acids under radical conditions

被引：93
|
作者：
Seo, Sangwon [1 ]
Taylor, John B. [2 ]
Greaney, Michael F. [1 ]
机构：
[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[2] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 66期
基金：
英国工程与自然科学研究理事会;
关键词：
COUPLING REACTIONS; CARBOXYLIC-ACIDS; DECARBOXYLATION; ARYLATION; KINETICS;
D O I：
10.1039/c2cc33306f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new approach to protodecarboxylation is described that enhances the substrate scope for benzoic acids. The reaction uses oxidative radical conditions to decarboxylate a variety of acids in acetonitrile.
引用
收藏
页码：8270 / 8272
页数：3
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