Enzyme recycling does not influence the enantioselectivity of the Pseudomonas cepacia lipase-catalyzed acylation of a racemic alcohol in organic solvents

被引:0
|
作者
Casati, S [1 ]
Caporali, M [1 ]
Ferraboschi, P [1 ]
Manzocchi, A [1 ]
Santaniello, E [1 ]
机构
[1] UNIV MILAN, DIPARTIMENTO CHIM & BIOCHIM MED, I-20133 MILAN, ITALY
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中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The enantioselectivity of the transesterification of racemic 2-methyl-3-phenyl-1-propanol 1 with vinyl acetate catalyzed by Pseudomonas cepacia lipase does not significantly change in benzene after four reactions using the same preparation of enzyme, whereas in chloroform the process becomes slower after the second reaction, the enantioselectivity being virtually unaffected.
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页码:81 / 83
页数:3
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