Density and viscosity of several pure and water-saturated ionic liquids

被引:754
|
作者
Jacquemin, J [1 ]
Husson, P [1 ]
Padua, AAH [1 ]
Majer, V [1 ]
机构
[1] Univ Clermont Ferrand, Lab Thermodynam Solut & Polymeres, CNRS, F-63177 Clermont Ferrand, France
关键词
D O I
10.1039/b513231b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Densities and viscosities were measured as a function of temperature for six ionic liquids (1-butyl-3-methylimidazolium hexafluorophosphate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, 1-ethyl-3-methylimidazolium ethylsulfate and butyltrimethylammonium bis(trifluoromethylsulfonyl)imide. The density and the viscosity were obtained using a vibrating tube densimeter from Anton Paar and a rheometer from Rheometrics Scientific at temperatures up to 393 K and 388 K with an accuracy of 10(-3) g cm(-3) and 1%, respectively. The effect of the presence of water on the measured values was also examined by studying both dried and water-saturated samples. A qualitative analysis of the evolution of density and viscosity with cation and anion chemical structures was performed.
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页码:172 / 180
页数:9
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