C-F bond formation with fluoride anions - highly selective iodofluorination of simple allenes

被引：19
|
作者：
Xue, Can [1 ]
Jiang, Xinpeng [1 ]
Fu, Chunling [1 ]
Ma, Shengming [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Lab Mol Recognit & Synth, Hangzhou 310027, Zhejiang, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 50期
基金：
中国国家自然科学基金;
关键词：
REDUCTIVE ELIMINATION; FLUOROHYDROXYLATION REACTION; CATALYZED FLUORINATION; EFFICIENT APPROACH; PHOSPHINE OXIDES; HALIDE EXCHANGE; PALLADIUM; CHEMISTRY; ALKENES; BROMOFLUORINATION;
D O I：
10.1039/c3cc42014k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly regioselective (up to 99 : 1) iodofluorination reaction of simple allenes occurs under mild conditions with Et3N center dot 3HF or Py center dot 9HF to afford 2-iodoalken-3-yl fluorides.
引用
收藏
页码：5651 / 5653
页数：3
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