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Defect-Type-Dependent Near-Infrared-Driven Photocatalytic Bacterial Inactivation by Defective Bi2S3 nanorods
被引:74
|作者:
Sun, Hongli
[1
]
Jiang, Zhifeng
[1
]
Wu, Dan
[3
]
Ye, Liqun
[4
]
Wang, Tianqi
[1
]
Wang, Bo
[1
]
An, Taicheng
[2
]
Wong, Po Keung
[1
,2
]
机构:
[1] Chinese Univ Hong Kong, Sch Life Sci, Shatin, Hong Kong, Peoples R China
[2] Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Publ Hlth & Environm Pollut Control, Guangzhou, Guangdong, Peoples R China
[3] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518000, Peoples R China
[4] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Engn Technol Res Ctr Henan Prov Solar Catalysis, Nanyang, Peoples R China
来源:
基金:
中国国家自然科学基金;
关键词:
bismuth;
defect engineering;
electronic structure;
photocatalysis;
sulfides;
OXYGEN VACANCIES;
CO2;
REDUCTION;
SOLAR-CELLS;
NANOSHEETS;
ELECTROCATALYST;
PHOSPHORUS;
ANATASE;
H2O;
O-2;
UV;
D O I:
10.1002/cssc.201802440
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Defect engineering is crucial in tailoring photocatalytic efficiency, but it suffers from uncertainty in determining the vacancy type and in which type of the vacancy can better promote the photocatalytic efficiency. In this study, Bi2S3 nanorods with bismuth or sulfur vacancies were synthesized to investigate their distinct effects on the electronic structure, electron-hole separation characteristics, and near-infrared (NIR)-driven photocatalytic bacterial inactivation activity. Both bismuth and sulfur vacancies can enhance the light absorption ability of Bi2S3. However, the lifetime of photoinduced electrons is extended by bismuth vacancies but shortened by sulfur vacancies. Owing to these tendencies, Bi2S3 with Bi vacancies fully inactivated 7 log E. coli cells within 40 min of NIR irradiation, displaying better NIR-driven photocatalytic bacterial inactivation efficiency than Bi2S3 with S vacancies. This study discloses the defect-type-dependent photocatalytic behaviors, providing new insights into designing highly efficient photocatalysts.
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页码:890 / 897
页数:8
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