Pyridine-type complexes of transition-metal halides XIV -: Part III.: Complexes with 2,4-, 2,6-, 3,4- and 3,5-lutidines

被引:0
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作者
Szécsényi, KM
Wadsten, T
Carson, B
Bencze, É
Liptay, G
机构
[1] Univ Novi Sad, Fac Sci, Inst Chem, YU-21000 Novi Sad, Yugoslavia
[2] Tech Univ Budapest, Dept Inorgan Chem, H-1521 Budapest, Hungary
[3] Heriot Watt Univ, Recruitment & Admiss Serv, Int Recruitment Off, Edinburgh EH14 4AS, Midlothian, Scotland
[4] Hungarian Acad Sci, Chem Res Ctr, Inst Isotopes & Surface Chem, H-1525 Budapest, Hungary
关键词
copper(II) halide-lutidine (dimethylpyridine) complexes; host-guest phenomenon;
D O I
暂无
中图分类号
O414.1 [热力学];
学科分类号
摘要
Compounds obtained by a solid-gas phase reactions between copper(II) chloride and bromide and 2,4-, 2,6- 3,4- and 3,5-lutidines were studied using thermogravimetry, far-infrared, electronic spectroscopy and X-ray diffraction. The results were compared with the corresponding data for the similar compounds with methylpyridines and 2,4,6-collidine. A special attention was paid to the host-guest phenomenon, a new structural feature of transition-metal halide complexes.
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页码:81 / 90
页数:10
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