Pyridine-type complexes of transition-metal halides -: Part XV.: Mn(II) chloride complexes with 3,4- and 3,5-lutidine

被引:0
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作者
Szécsényi, KM
Wadsten, T
Kovács, A
Liptay, G
机构
[1] Univ Novi Sad, Fac Sci, Dept Chem, YU-21000 Novi Sad, Serbia Monteneg, Serbia
[2] Budapest Univ Technol & Econ, Dept Inorgan Chem, H-1521 Budapest, Hungary
[3] Budapest Univ Technol & Econ, Inst Gen & Analyt Chem, Hungarian Acad Sci, Res Grp Tech Analyt Chem, H-1521 Budapest, Hungary
关键词
FT-IR spectrometry; host-guest phenomenon; manganese(II) chloride-lutidine (dimethylpyridine) complexes;
D O I
10.1023/B:JTAN.0000027190.32572.8b
中图分类号
O414.1 [热力学];
学科分类号
摘要
Manganese(II) chloride complexes with 3,4- and 3,5-lutidine have been prepared. The crystal symmetry and cell dimensions have been calculated on the basis of powder diffraction data. The compounds were characterised also by FT-IR spectrometry. The thermal decomposition of the complexes has been studied by thermogravimetiy and DSC. By plotting densities vs. molar mass, the diagram obtained has correspondence to similar observations in other solid metal-lutidine complex systems.
引用
收藏
页码:965 / 974
页数:10
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