Esterification of 5-Norbornene-2,3-dicarboxylic anhydride Under Titanium catalyst

被引：5
|
作者：
Park, Sung-Ho [1 ]
Park, Jun-Seong [1 ]
Ko, Tae-Won [1 ]
Park, Yong-Sung [1 ]
Woo, Je-Wan [1 ]
机构：
[1] Sangmyung Univ, Seoul, South Korea
来源：
ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5 | 2013年 / 634-638卷
关键词：
Esterification; Norbornene derivatives; Titanium(IV) isopropoxide; Diels-Alder reaction; Retro Diels-Alder reaction; PHTHALIC-ANHYDRIDE; 2-ETHYLHEXANOL;
D O I：
10.4028/www.scientific.net/AMR.634-638.642
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Norbornene dicarboxylate was synthesized through esterification under titanium catalyst. The alcohols are 2-ethyl-1-hexanol, n-octanol, 3,5,5-trimethyl-1-hexanol, and n-decanol. The Structures of compounds were identified by H-1-NMR, and then components were identified by high performance liquid chromatography (HPLC). The yield and purity was over 90 % and 95 %, and color of compounds was colorless or light yellow. The maleate as a by-product was occured by the retro Diels-Alder reaction.
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页码：642 / 646
页数：5
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