Esterification of 5-Norbornene-2,3-dicarboxylic anhydride Under Titanium catalyst

被引：5

作者：

Park, Sung-Ho ^{[1
]}

Park, Jun-Seong ^{[1
]}

Ko, Tae-Won ^{[1
]}

Park, Yong-Sung ^{[1
]}

Woo, Je-Wan ^{[1
]}

机构：

[1] Sangmyung Univ, Seoul, South Korea

来源：

ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5 | 2013年 / 634-638卷

关键词：

Esterification; Norbornene derivatives; Titanium(IV) isopropoxide; Diels-Alder reaction; Retro Diels-Alder reaction; PHTHALIC-ANHYDRIDE; 2-ETHYLHEXANOL;

D O I：

10.4028/www.scientific.net/AMR.634-638.642

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Norbornene dicarboxylate was synthesized through esterification under titanium catalyst. The alcohols are 2-ethyl-1-hexanol, n-octanol, 3,5,5-trimethyl-1-hexanol, and n-decanol. The Structures of compounds were identified by H-1-NMR, and then components were identified by high performance liquid chromatography (HPLC). The yield and purity was over 90 % and 95 %, and color of compounds was colorless or light yellow. The maleate as a by-product was occured by the retro Diels-Alder reaction.

引用

页码：642 / 646

页数：5

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