Analysis of sexual assault evidence by desorption electrospray ionization mass spectrometry

被引：32
|
作者：
Mirabelli, Mario F. [1 ,2 ]
Chramow, Alexander [1 ]
Cabral, Elaine C. [1 ]
Ifa, Demian R. [1 ]
机构：
[1] York Univ, Dept Chem, N York, ON M3J 1P3, Canada
[2] Univ Calabria, Dept Chem, I-87030 Cosenza, Italy
来源：
JOURNAL OF MASS SPECTROMETRY | 2013年 / 48卷 / 07期
基金：
加拿大自然科学与工程研究理事会;
关键词：
ambient ionization; forensics; condoms; DESI; polymers; PERSONAL LUBRICANTS; CONDOM LUBRICANTS; FORENSIC ANALYSIS; IDENTIFICATION; POLYMERS; TIME;
D O I：
10.1002/jms.3205
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Desorption electrospray ionization mass spectrometry (DESI-MS) is employed in the forensic analysis of chemical components present in condoms and imaging of latent fingerprints as circumstantial evidence of sexual assault. Polymers such as nonoxynol-9, polyethylene glycol, and polydimethylsiloxane, as well as small molecules additives such as N-methylmorpholine, N-octylamine, N,N-dibutyl formamide, and isonox 132, commonly used in lubricated condom formulations, were successfully characterized by DESI. The results suggest that DESI-MS is useful for identification of this type of evidence, and it has advantages over conventional extractive techniques, in terms of speed of analysis and ease of use. Copyright (c) 2013 John Wiley & Sons, Ltd.
引用
收藏
页码：774 / 778
页数：5
相关论文
共 50 条
  • [31] Desorption electrospray ionization mass spectrometry for direct analysis of clinic urine samples
    Chen, Huan-Wen
    Li, Ming
    Zhou, Jian-Guang
    Fei, Qiang
    Jiang, Jie
    Jin, Qin-Han
    Zhang, Tian-Mu
    Zhang, Xie
    [J]. Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities, 2006, 27 (08): : 1439 - 1442
  • [32] Forensic analysis of inks by imaging desorption electrospray ionization (DESI) mass spectrometry
    Ifa, D. R.
    Gumaelius, L. M.
    Eberlin, L. S.
    Manicke, N. E.
    Cooks, R. G.
    [J]. ANALYST, 2007, 132 (05) : 461 - 467
  • [33] Laser desorption ionization versus electrospray ionization mass spectrometry:: Applications in the analysis of cluster anions
    Dyson, PJ
    Hearley, AK
    Johnson, BFG
    McIndoe, JS
    Langridge-Smith, PRR
    [J]. JOURNAL OF CLUSTER SCIENCE, 2001, 12 (01) : 273 - 283
  • [34] Laser Desorption Ionization Versus Electrospray Ionization Mass Spectrometry: Applications in the Analysis of Cluster Anions
    Paul J. Dyson
    Andrew K. Hearley
    Brian F. G. Johnson
    J. Scott McIndoe
    Patrick R. R. Langridge-Smith
    [J]. Journal of Cluster Science, 2001, 12 : 273 - 283
  • [35] Coupling desorption electrospray ionization with ion mobility/mass spectrometry for analysis of protein structure:: Evidence for desorption of folded and denatured states
    Myung, S
    Wiseman, JM
    Valentine, SJ
    Takáts, Z
    Cooks, RG
    Clemmer, DE
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (10): : 5045 - 5051
  • [36] Tissue imprint imaging by desorption electrospray ionization mass spectrometry
    Ifa, Demian R.
    Srimany, Amitava
    Eberlin, Livia S.
    Naik, Hemanta R.
    Bhat, Vasudeva
    Cooks, R. Graham
    Pradeep, T.
    [J]. ANALYTICAL METHODS, 2011, 3 (08) : 1910 - 1912
  • [37] Ambient molecular imaging by desorption electrospray ionization mass spectrometry
    Justin M Wiseman
    Demian R Ifa
    Andre Venter
    R Graham Cooks
    [J]. Nature Protocols, 2008, 3 : 517 - 524
  • [38] Electrode-assisted desorption electrospray ionization mass spectrometry
    Ozdemir, Abdil
    Chen, Chung-Hsuan
    [J]. JOURNAL OF MASS SPECTROMETRY, 2010, 45 (10): : 1203 - 1211
  • [39] Ambient molecular imaging by desorption electrospray ionization mass spectrometry
    Wiseman, Justin M.
    Ifa, Demian R.
    Venter, Andre
    Cooks, R. Graham
    [J]. NATURE PROTOCOLS, 2008, 3 (03) : 517 - 524
  • [40] Improved imaging resolution in desorption electrospray ionization mass spectrometry
    Kertesz, Vilmos
    Van Berkel, Gary J.
    [J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2008, 22 (17) : 2639 - 2644
12345