Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS2O2N2 Skeletons

被引：31
|
作者：
Metz, Stefan [1 ]
Burschka, Christian [1 ]
Tacke, Reinhold [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 28期
关键词：
Coordination chemistry; Hexacoordination; Silicon; Sulfur; Tridentate ligands;
D O I：
10.1002/ejic.200800657
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)(4). All the compounds synthesized were structurally characterized by single-crystal X-ray diffraction and/or solid-state NMR spectroscopy. In addition, most of the compounds were characterized by solution NMR spectroscopy. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
引用
收藏
页码：4433 / 4439
页数：7
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