Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS2O2N2 Skeletons

被引：31

作者：

Metz, Stefan ^{[1
]}

Burschka, Christian ^{[1
]}

Tacke, Reinhold ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 28期

关键词：

Coordination chemistry; Hexacoordination; Silicon; Sulfur; Tridentate ligands;

D O I：

10.1002/ejic.200800657

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO)(4). All the compounds synthesized were structurally characterized by single-crystal X-ray diffraction and/or solid-state NMR spectroscopy. In addition, most of the compounds were characterized by solution NMR spectroscopy. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

引用

页码：4433 / 4439

页数：7

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