From Olefins to Alcohols: Efficient and Regioselective Ruthenium-Catalyzed Domino Hydroformylation/Reduction Sequence

被引：93
|
作者：
Fleischer, Ivana [1 ]
Dyballa, Katrin Marie [1 ,2 ]
Jennerjahn, Reiko [1 ]
Jackstell, Ralf [1 ]
Franke, Robert [2 ,3 ]
Spannenberg, Anke [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
[2] Evon Ind AG, D-45772 Marl, Germany
[3] Ruhr Univ Bochum, Lehrstuhl Theoret Chem, D-44780 Bochum, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 10期
基金：
瑞士国家科学基金会;
关键词：
alcohols; domino reactions; homogeneous catalysis; hydroformylation; ruthenium; LOW-PRESSURE HYDROFORMYLATION; CARBON-DIOXIDE; ASYMMETRIC HYDROFORMYLATION; SELECTIVE HYDROFORMYLATION; 1-HEXENE HYDROFORMYLATION; BIFUNCTIONAL CATALYST; LINEAR ALCOHOLS; COMPLEXES; ALKENES; LIGANDS;
D O I：
10.1002/anie.201207133
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Exploring the alternatives: Ruthenium imidazoyl phosphine complexes catalyze the domino hydroformylation/reduction of alkenes to alcohols in good yields and with good selectivities (see scheme). Linear aliphatic alcohols are synthesized under reaction conditions typically used in industrial hydroformylations. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2949 / 2953
页数：5
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