Towards the Development of a Selective Ruthenium-Catalyzed Hydroformylation of Olefins

被引：60
|
作者：
Fleischer, Ivana [1 ]
Wu, Lipeng [1 ]
Profir, Irina [1 ]
Jackstell, Ralf [1 ]
Franke, Robert [2 ,3 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29A, D-18059 Rostock, Germany
[2] Evon Ind AG, D-45772 Marl, Germany
[3] Lehrstuhl Theoret Chem, D-44780 Bochum, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 32期
基金：
瑞士国家科学基金会;
关键词：
aldehydes; carbonylation; hydroformylation; phosphine; ruthenium; REGIOSELECTIVE ISOMERIZATION-HYDROFORMYLATION; FUNCTIONALIZED GAMMA-BUTYROLACTONES; INTERNAL OLEFINS; LINEAR ALDEHYDES; BETA; GAMMA-UNSATURATED KETONES; ASYMMETRIC HYDROFORMYLATION; TRANSFER HYDROGENATION; BIFUNCTIONAL CATALYST; PALLADIUM COMPLEXES; CARBON-MONOXIDE;
D O I：
10.1002/chem.201300899
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ruthenium-catalyzed hydroformylation of 1- and 2-octene to give preferentially the corresponding linear aldehyde is reported. The catalyst system comprising of Ru-3(CO)(12) and an imidazole-substituted monophosphine ligand allows for high chemo-and regioselectivity. The hydroformylation proceeds with unprecedented rates for a ruthenium-based catalyst.
引用
收藏
页码：10589 / 10594
页数：6
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