Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

被引：8
|
作者：
Boulanger, Jerome [1 ]
Bricout, Herve [1 ]
Tilloy, Sebastien [1 ]
Fihri, Aziz [2 ]
Len, Christophe [3 ]
Hapiot, Frederic [1 ]
Monflier, Eric [1 ]
机构：
[1] Univ Lille Nord France, UCCS, UArtois, CNRS,Face Jean Perrin,UMR 8181, F-62307 Lens, France
[2] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr KCC, Thuwal 23955, Saudi Arabia
[3] Univ Technol Compiegne, Transformat Integrees Mat Renouvelable EA UTC ESC, Ctr Rech Royallieu, F-60205 Compiegne, France
来源：
CATALYSIS COMMUNICATIONS | 2012年 / 29卷
关键词：
Water soluble phosphane; Aqueous catalysis; Hydroformylation; HYDROFORMYLATION; CYCLODEXTRINS; PHOSPHINE;
D O I：
10.1016/j.catcom.2012.09.019
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：77 / 81
页数：5
相关论文
共 50 条
  • [21] WATER-SOLUBLE PHOSPHINES - SYNTHESIS AND USE IN CATALYSIS
    SINOU, D
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1987, (03): : 480 - 486
  • [22] Synthesis and reactivity of water-soluble organometallic complexes containing hydrophilic pyridine-imine ligands.
    Buffin, BP
    Ojewrole, AO
    Blondin, JS
    Barker, EC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U802 - U802
  • [23] Water-soluble organometallic complexes of tantalum:: Can alkyl and aqua ligands coexist in its coordination sphere?
    Conde, Ana
    Fandos, Rosa
    Otero, Antonio
    Rodriguez, Ana
    ORGANOMETALLICS, 2007, 26 (07) : 1568 - 1570
  • [24] Synthesis of Water-Soluble Dendritic Phosphine Ligands and Their Application to Hydration of Alkynes in Aqueous Media
    Fujita, Ken-ichi
    Kujime, Masato
    Muraki, Takahito
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2009, 82 (02) : 261 - 266
  • [25] Synthesis of water-soluble CAAC catalyst ligands
    Kovacs, Ervin
    Turczel, Gabor
    Nagyhazi, Marton
    Szalas, Gabor
    Saghy, Peter
    Tuba, Robert
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [26] AQUEOUS ORGANOMETALLIC CATALYSIS
    JAMES, BR
    CHEMICAL & ENGINEERING NEWS, 1995, 73 (26) : 5 - 5
  • [27] WATER-SOLUBLE PHOSPHINES AS LIGANDS FOR HYDROFORMYLATION CATALYSTS
    BAHRMANN, H
    BACH, H
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1987, 30 (3-4): : 611 - 614
  • [28] Self-assembled supramolecular bidentate ligands for aqueous organometallic catalysis
    Machut, Cecile
    Patrigeon, Julien
    Tilloy, Sebastien
    Bricout, Herve
    Hapiot, Frederic
    Monflier, Eric
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (17) : 3040 - 3042
  • [29] Water-soluble and water-stable organometallic gold(II) complexes
    Mohr, Fabian
    Sanz, Sergio
    Tiekink, Edward R. T.
    Laguna, Mariano
    ORGANOMETALLICS, 2006, 25 (12) : 3084 - 3087
  • [30] Novel ligands for organometallic catalysis
    Wicker, Benjamin
    Gass, Kaycee
    St Lawrence, Matthew
    Wang, Yufei
    Davis, James
    Sykora, Richard
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
12345