Direct Enhancement of Nuclear Singlet Order by Dynamic Nuclear Polarization

被引:86
|
作者
Tayler, Michael C. D. [1 ]
Marco-Rius, Irene [2 ,3 ]
Kettunen, Mikko I. [2 ,3 ]
Brindle, Kevin M. [2 ,3 ]
Levitt, Malcolm H. [1 ]
Pileio, Giuseppe [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[2] Univ Cambridge, Dept Biochem, Cambridge CB2 1GA, England
[3] Canc Res UK Cambridge Res Inst, Cambridge CB2 0RE, England
基金
英国工程与自然科学研究理事会; 欧洲研究理事会;
关键词
PARA-HYDROGEN; STATE;
D O I
10.1021/ja302814e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hyperpolarized singlet order is available immediately after dissolution DNP, avoiding need for additional preparation steps. We demonstrate this procedure on a sample of [1,2-C-13(2)]pyruvic acid.
引用
收藏
页码:7668 / 7671
页数:4
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