DNA Nanocages Swallow Gold Nanoparticles (AuNPs) to Form AuNP@DNA Cage Core-Shell Structures

被引:88
|
作者
Zhang, Chuan [1 ]
Li, Xiang [1 ]
Tian, Cheng [1 ]
Yu, Guimei [2 ,3 ]
Li, Yulin [1 ]
Jiang, Wen [2 ,3 ]
Mao, Chengde [1 ]
机构
[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
[2] Purdue Univ, Markey Ctr Struct Biol, W Lafayette, IN 47907 USA
[3] Purdue Univ, Dept Biol Sci, W Lafayette, IN 47907 USA
关键词
DNA nanostructures; self-assembly; nanocages; gold nanoparticles; NANOSTRUCTURES; NANOTECHNOLOGY; OCTAHEDRON; MOLECULE; ORIGAMI; SHAPES;
D O I
10.1021/nn406039p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
DNA offers excellent programming properties to nanomaterials syntheses. Host guest interaction between DNA nanostructures and inorganic nanoparticles (NPs) is of particular interest because the resulting complexes would possess both programming properties intrinsic to DNA and physical properties associated with inorganic NPs, such as plasmonic and magnetic features. Here, we report a class of core shell complexes (AuNP@DNA cages): hard gold NPs (AuNPs) are encapsulated in geometrically well-defined soft DNA nanocages. The AuNP guest can be further controllably released from the host (DNA nanocages), pointing to potential applications in surface engineering of inorganic NPs and cargo delivery of DNA nanocages.
引用
收藏
页码:1130 / 1135
页数:6
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