Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements

被引：139

作者：

Hill, Nicholas J. ^{[2
]}

Vargas-Baca, Ignacio

Cowley, Alan H. ^{[1
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

DALTON TRANSACTIONS | 2009年 / 02期

基金：

加拿大自然科学与工程研究理事会; 美国国家科学基金会;

关键词：

TRANSITION-METAL-COMPLEXES; AMIDO-IMINO LIGAND; MOLECULAR-STRUCTURES; CRYSTAL-STRUCTURES; CALCIUM COMPLEXES; SINGLE-ELECTRON; IPR-DAB; STRUCTURAL-CHARACTERIZATION; LIVING POLYMERIZATION; COPPER(II) COMPLEXES;

D O I：

10.1039/b815079f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(imino)acenaphthenes (BIAN) have been known for many years. However, it is only since the 1990s that such compounds have been recognized as robust ligands for the support of catalytically active transition metal centers. More recently, the unique stereoelectronic properties of the BIAN ligand class are beginning to be appreciated and exploited for some fascinating new developments in synthetic, structural and catalytic s- and p-block chemistry.

引用

页码：240 / 253

页数：14

共 34 条

[31] Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C-E Bond Formation and C-O Bond Cleavage Processes in the Reactions of [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)] with Several p-Block Elements (E) and Their Hydride Derivatives
Esther Garcia, M.
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ORGANOMETALLICS, 2010, 29 (09) : 2157 - 2165
[32] Synthesis and coordination chemistry of the first water-soluble dithio-bis(phosphine) ligands [(HOH2C)(2)P(CH2)(2)S-X-S(CH2)(2)P(CH2OH)(2)] (X=(CH2)(3) or C6H4). X-ray crystal structure of [Pd(HOH2C)(2)P(CH2)(2)S(CH2)(3)S(CH2)(2)P(CH2OH)(2)](Cl)(2)
Smith, CJ
Reddy, VS
Karra, SR
Katti, KV
Barbour, LJ
INORGANIC CHEMISTRY, 1997, 36 (09) : 1786 - 1791
[33] Synthesis and Coordination Chemistry of the First Water-Soluble Dithio-Bis(phosphine) Ligands [(HOH2C)2P(CH2)2S-X- S(CH2)2P-(CH2OH)2] (X = (CH2)3 or C6H4). X-ray Crystal Structure of [Pd(HOH2C)2P(CH2)2S-(CH2)3S(CH2 )2P( CH2OH)2](Cl)2
Smith, C. J.
Reddy, V. S.
Karra, S. R.
Katti, K. V.
Inorganic Chemistry, 36 (09):
[34] COORDINATION CHEMISTRY OF THE RHENIUM ORGANODIAZENIDO CORE WITH FACULTATIVE TETRADENTATE LIGANDS POSSESSING THIOLATE AMINE AND THIOLATE THIOETHER DONOR SETS - CRYSTAL AND MOLECULAR-STRUCTURES OF [RE(SCH2CH2NMECH2CH2NMECH2CH2S)(N2COC6H4-P-CL)(PPH3)].CH3OH,[RE(SCH2CH2S(CH2)3SCH2CH2S)(N2COPH)(PPH3)], AND [RE(SCH2CH2S(CH2)3SCH2CH2S)(N2CO2ME)(PPH3)].CH2CL2 AND A COMPARISON WITH THE STRUCTURE OF THE OXIDATION-PRODUCT [N,N'-DIMETHYL-N,N'-BIS(SULFINATOETHYL)ETHYLENEDIAMINE-S,N,N',O'][(2-CHLOROPHENYL)-DIAZENIDO](TRIPHENYLPHOSPHINE)RHENIUM(I), [RE(O2SCH2CH2NMECH2CH2NMECH2CH2SO2)(N2C6H4-O-CL)(PPH3)]E
NICHOLSON, T
ZUBIETA, J
INORGANIC CHEMISTRY, 1987, 26 (13) : 2094 - 2101

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