Access to the Protoilludane Core by Gold-Catalyzed Allene-vinylcyclopropane Cycloisomerization

被引：41
|
作者：
Pitaval, Anthony [1 ]
Leboeuf, David [1 ]
Ceccon, Julien [1 ]
Echavarren, Antonio M. [1 ,2 ]
机构：
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[2] Univ Rovira & Virgili, Dept Qukm Analkt & Qukm Organ, E-43007 Tarragona, Spain
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 17期
基金：
欧洲研究理事会;
关键词：
ENANTIOSELECTIVE SYNTHESIS; CYCLOADDITIONS; PLATINUM;
D O I：
10.1021/ol402188b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Gold(I)-catalyzed allene-vinylcyclopropane cycloisomerization leads to the tricyclic framework of the protoilludanes in a single step by a reaction that involves a cyclopropane ring expansion and a Prins cyclization.
引用
收藏
页码：4580 / 4583
页数：4
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