Synthesis and transition metal chemistry of new bromo- and alkyl substituted phosphinite ligands

被引：2

作者：

Naik, Susmita ^{[1
]}

Durganna, Nallbothula ^{[1
]}

Mobin, Shaik M. ^{[2
]}

Mague, Joel T. ^{[3
]}

Balakrishna, Maravanji S. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Phosphorus Lab, Bombay 400076, Maharashtra, India

[2] Indian Inst Technol, Natl Single Crystal Xray Diffract Facil, Bombay 400076, Maharashtra, India

[3] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

POLYHEDRON | 2012年 / 38卷 / 01期

关键词：

Phosphinite; Ruthenium; Palladium; Gold complexes; Chloro-bridged dimer; Crystal structure; CROSS-COUPLING REACTIONS; HIGH-ACTIVITY CATALYSTS; PALLADIUM(II) COMPLEXES; NICKEL-COMPLEXES; ARYL CHLORIDES; C-C; SUZUKI; REACTIVITY; BIS(PHOSPHINITE); OLIGOMERIZATION;

D O I：

10.1016/j.poly.2012.02.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ligands Ph2P(OAr) (Ar = 2,4,6-C6H2Br3, 1; Ar = C6H3(o-OMe)(p-C3H6), 2) were prepared by treating PPh2CI with tribromo phenol and eugenol, respectively, in good yields. The reaction of Ph2P(OAr) with Pd(COD)Cl-2] in 2:1 molar ratio yielded trans-[Pd{PPh2(OAr)}Cl-2] (4) and cis-[Pd{PPh2(OAr)}Cl-2] (5), respectively. The chloro-bridged dipalladium complex [Pd-2{PPh2(OAr)}(2)Cl-4 (6) was obtained in the 11 reaction between 2 and [Pd(COD)Cl-2], along with 5 as a minor product. Mononuclear complexes, [Au {PPh2(OAr)}Cl] (Ar = 2,4,6-C6H2Br3, 7; Ar = C6H3(o-OMe](p-C3H5), 8) and [(Ru(eta(6)-p-cym){PPh2(OAr)Cl (2)} (9) were prepared by reacting ligands 1 and 2 with [AuCl(SMe2)] and [(Ru(eta(6)-p-cym)Cl-2](2), respectively. All the complexes were characterized by P-31. H-1 NMR and elemental analyses data. (C) 2012 Elsevier Ltd. All rights reserved.

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页码：97 / 102

页数：6

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