A new ruthenium(II) hydride carbonyl complex with pyrimidine ligand

被引：7

作者：

Malecki, J. G. ^{[1
]}

Kruszynski, R. ^{[2
]}

Mazurak, Z. ^{[3
]}

机构：

[1] Silesian Univ, Inst Chem, Dept Inorgan & Coordinat Chem, PL-40006 Katowice, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland

[3] Polish Acad Sci, Ctr Polymer Chem, PL-41819 Zabrze, Poland

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 14期

关键词：

ruthenium hydride carbonyl complexes; pyrimidine; X-ray structure; UV-Vis spectrum; luminescence; DFT calculations;

D O I：

10.1080/00958970801905262

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [RuHCl(CO)(PPh3)(3)] with pyrimidine gives [RuHCl(CO)(PPh3)(2)(C4H4N2)]. The compound has been studied by IR, UV-Vis and X-ray crystallography. The molecular orbital diagram of the complex has been calculated with density functional theory (DFT). The spin-allowed singlet-singlet electronic transitions of the complex have been calculated with time-dependent DFT method, and the UV-Vis spectrum of the compound has been discussed on this basis. Emission of the compound was studied.

引用

页码：2186 / 2196

页数：11

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