Thermodynamic assessment of the Ca-Pb system

被引:16
|
作者
Cartigny, Y [1 ]
Fiorani, JM [1 ]
Maître, A [1 ]
Vilasi, M [1 ]
机构
[1] Univ Nancy 1, UMR 7555, Lab Chim SOlide Mineral, F-54506 Vandoeuvre Les Nancy, France
关键词
calcium-lead system; thermodynamic modelling; association model;
D O I
10.1016/j.tca.2004.01.001
中图分类号
O414.1 [热力学];
学科分类号
摘要
Thermodynamic modelling of the Ca-Pb system was carried out. The thermodynamic parameters were determined using available experimental information: phase diagram data and thermodynamic quantities. For this system, the liquid phase was described from the association model with the "Ca2Pb" associated complex. The calculations well restore experimental values. All the results so-obtained (optimised thermodynamic parameters and calculated phase diagram) are reported in this paper and discussed. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:197 / 202
页数:6
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