Synthesis of (1R,3S,5S)-1,3,8-trimethyl-2,9-dioxabicyclo[3.3.1]non-7-ene, the male pheromone of a hepialid moth Endoclita excrescens, and its enantiomer

被引：2
|
作者：
Marukawa, K [1 ]
Mori, K [1 ]
机构：
[1] Sci Univ Tokyo, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan
来源：
CHEMISTRY LETTERS | 2002年 / 01期
关键词：
D O I：
10.1246/cl.2002.40
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Both (1R,3S,5S)- and (1S,3R,5R)-isomers of 1,3,8-trimethyl-2,9-dioxabicyclo[3.3.1]non-7-ene were synthesized by starting from (S)- and (R)-isomers of ethyl 3-hydroxybutanoate, respectively. The (1R,3S,5S)-isomer was identified as the male sex pheromone of a Japanese hepialid moth, Endoclita excrescens.
引用
收藏
页码：40 / 41
页数：2
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