Superplastic nanocrystalline ceramics at room temperature and high strain rates

被引:25
|
作者
Zhang, J. Y. [1 ]
Sha, Z. D. [1 ]
Branicio, P. S. [1 ]
Zhang, Y. W. [1 ]
Sorkin, V. [1 ]
Pei, Q. X. [1 ]
Srolovitz, D. J. [2 ,3 ]
机构
[1] Agcy Sci Technol & Res, Inst High Performance Comp, Singapore 138632, Singapore
[2] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[3] Univ Penn, Dept Mech Engn & Appl Mech, Philadelphia, PA 19104 USA
关键词
Nanostructured ceramics; Superplasticity; High strain rates; Grain size effect; Silicon carbide; SIC NANOWIRES; MOLECULAR-DYNAMICS; PLASTIC-FLOW; DIFFUSION; DUCTILITY; CARBIDE; CREEP;
D O I
10.1016/j.scriptamat.2013.06.017
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Tensile-loading molecular dynamics simulations show that nanocrystalline SiC not only becomes ductile, but can be superplastically deformed at room temperature when grain sizes are reduced to d similar to 2 nm. The calculated strain rate sensitivity, 0.67, implies a superplastic ceramic able to attain strains of up to 1000% at room temperature and typical strain rates (similar to 10(-2) s(-1)). The origin of the superplasticity is linked to an unusually steep rise in creep rate to 10(6) s(-1) for d = 2 nm. The results explain recent observations in SiC nanowires and suggest novel opportunities for structural ceramics. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:525 / 528
页数:4
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