A new twist to 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine complexes of silver(I)

被引：21
|
作者：
Constable, Edwin C. [1 ]
Housecroft, Catherine E. [1 ]
Neuburger, Markus [1 ]
Reymann, Sebastien [1 ]
Schaffner, Silvia [1 ]
机构：
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
来源：
CRYSTENGCOMM | 2008年 / 10卷 / 08期
关键词：
D O I：
10.1039/b803006e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dinuclear complex [Ag-2(1)(3)](2+) has been isolated as the triflate salt from the reaction of silver(I) triflate with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (1) in acetonitrile. The single crystal structure of [Ag-2(1)(3)][CF3SO3](2)center dot MeCN reveals a trigonal prismatic coordination environment for each silver(I) centre. The isolation of [Ag-2(1)(3)][CF3SO3](2)center dot MeCN contrasts with our earlier observation that crystalline [Ag-2(1)(2)][CF3SO3](2) can be isolated from a 1 : 1 reaction of AgCF3SO3. These data are discussed in the context of other published observations of similar systems, and the present results suggest that the reasons governing the assembly of a given structural architecture between Ag+ and 1 are more subtle than simply the choice of anion.
引用
收藏
页码：991 / 995
页数：5
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