Determination of Lead using 2, 5-Dimercapto-1, 3, 4-Thiodiazole (DMTD)

被引:0
|
作者
Imtiaz, Naz [1 ]
Butt, Muhammad Tahir [1 ]
Khan, Rauf Ahmad [1 ]
Iqbal, Javed [1 ]
机构
[1] Ctr Environm Protect Studies, Lahore, Pakistan
来源
关键词
SPECTROPHOTOMETRIC DETERMINATION; SOIL;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new spectrophotometric method which is fairly selective, non extractive, is described here for the determination of lead based upon its colour reaction with 2,5- dimercapto-1, 3,4-thiodiazole (DMTD). According to this lead (II) can be determined within the range from 1.0 to 50 mu g per mL in a slightly acidic media (0.005 M HCl), to give a greenish yellow chelate complex, which has an absorption at 375 nm. The reaction proceeds fastly and color remains stable. While no special conditions are followed. The method is recommended for its routine use and is quite accurate, precise, and sensitive. Effect of Foreign ions is also studied at 40 mu g/mL of lead.
引用
收藏
页码:1111 / 1114
页数:4
相关论文
共 50 条
  • [41] Corrosion protection of bronze using 2,5-dimercapto-1,3,4-thiadiazole as organic inhibitor: spectroscopic and electrochemical investigations
    W. Qafsaoui
    A. Et Taouil
    M. W. Kendig
    O. Heintz
    H. Cachet
    S. Joiret
    H. Takenouti
    Journal of Applied Electrochemistry, 2019, 49 : 823 - 837
  • [42] Electrochemical determination of Pb(II) at a gold electrode modified with a self-assembled monolayer of 2,5-dimercapto-1,3,4-thiadiazole
    Yun Wu
    Nian Bing Li
    Hong Qun Luo
    Microchimica Acta, 2008, 160 : 185 - 190
  • [43] 2,5-Disubstituted structures of 1,3,4-oxadiazole and 1,3,4-thiodiazole for anti-inflammatory potential: DFT approach for the structural aspects
    Veeramani, Vairaperumal
    Ganesh, Pothapragada S. K. Prabhakar
    Bharanidharan, Sarangapani
    Muthuraja, Perumal
    Govindasamy, Chandramohan
    Rajamohan, Rajaram
    JOURNAL OF MOLECULAR STRUCTURE, 2024, 1318
  • [44] Electrochemical determination of Pb(II) at a gold electrode modified with a self-assembled monolayer of 2,5-dimercapto-1,3,4-thiadiazole
    Wu, Yun
    Li, Nian Bing
    Luo, Hong Qun
    MICROCHIMICA ACTA, 2008, 160 (1-2) : 185 - 190
  • [45] Selective Adsorption of AuIII from Aqueous Solution Using 2,5-Dimercapto-1,3,4-thiadiazole Modified Persimmon Tannin
    Zhang, Sijing
    Ji, Yongliang
    Ao, Fengjiao
    Wang, Yongping
    Zhao, Junxue
    Chen, Shuangli
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2018, 29 (07) : 1487 - 1498
  • [46] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [NME(4)](4)[MN-2(C3S5)(4)](C3S52-=4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONATE)
    TAMURA, H
    TANAKA, S
    MATSUBAYASHI, G
    MORI, W
    INORGANICA CHIMICA ACTA, 1995, 232 (1-2) : 51 - 55
  • [47] A 2:1 mixture of tetrabutylammonium bis(4,5-dimercapto-1,3-dithiole-2-thionato)-nickelate(II) and its 2-selenone analogue
    Fun, HK
    Sivakumar, K
    Zuo, JL
    Yao, TM
    You, XZ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 312 - 315
  • [48] A New Molecular Metal: (NHMe3)(0.5)[Ni(dmit)(2)] (dmit=4,5-Dimercapto-1,3-dithia-2-thione)
    Tejel, Cristina
    Pomarede, Brigitte
    Legros, Jean-Pierre
    Valade, Lydie
    Cassoux, Patrick
    CHEMISTRY OF MATERIALS, 1989, 1 (06) : 578 - 580
  • [49] CHEMISTRY OF 2,1,3-THIODIAZOLE .18. ESTERS ANDAMIDES OF 5,7-DIHALOBENZO-2,1,3-THIODIAZOLE-4-HYDROXYACETIC ACIDS
    PESIN, VG
    LOTSMANENKO, IA
    KHALETSKII, AM
    JOURNAL OF GENERAL CHEMISTRY USSR, 1963, 33 (04): : 1082 - &
  • [50] Corrosion Inhibition of Brazing Cu-Ag Alloy with 1,2,3-Benzotriazole and 2,5-Dimercapto-1,3,4-Thiadiazole
    Rahmani, Hooman
    Meletis, Efstathios, I
    CORROSION, 2021, 77 (01) : 29 - 39