A convenient synthesis of (E)-β-hydroxyvinyltrimethylsilanes via 3,3-bis(trimethylsilyl)propene

被引：8
|
作者：
Princet, B [1 ]
Anselme, G [1 ]
Pornet, J [1 ]
机构：
[1] Univ Poitiers, Organ Synth Lab, F-86022 Poitiers, France
来源：
SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 19期
关键词：
D O I：
10.1080/00397919908085961
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
3,3-Bis(trimethylsilyl) propene, easily obtained by semi-hydrogenation from the recently reported (trimethylsilyl)prop-2-yne, reacts cleanly with aldehydes in the presence of titanium tetrachloride providing a new way to (E)-beta-hydroxyvinyltrimethylsilanes
引用
收藏
页码：3329 / 3340
页数：12
相关论文
共 50 条
  • [31] PROPARGYLIC SILANES - CONVENIENT SYNTHESES OF 1-TRIMETHYLSILYL-2-ALKYNES, 1,3-BIS[TRIMETHYLSILYL]-1-ALKYNES, AND 3-TRIMETHYLSILYL-1-ALKYNES
    RAJAGOPALAN, S
    ZWEIFEL, G
    SYNTHESIS-STUTTGART, 1984, (02): : 111 - 112
  • [32] Catalyst Free Synthesis of Bis(Indolyl)Methanes and 3,3-Bis(Indolyl)oxindoles in Aqueous Ethyl Lactate
    Gao, Ge
    Han, Yi
    Zhang, Zhan-Hui
    CHEMISTRYSELECT, 2017, 2 (35): : 11561 - 11564
  • [33] Rhodium-catalyzed hydroformylation of 1,1-bis(p-fluorophenyl)ethene and 3,3-bis(p-fluorophenyl)propene
    Botteghi, C
    Paganelli, S
    Marchetti, M
    Pannocchia, P
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) : 233 - 241
  • [34] 3,3-BIS(INDOLYL-3)PHTHALIDES AND ITS PROPERTIES
    KONYUKHOVA, TM
    ABRAMENKO, PI
    KIRILLOVA, KM
    KAZYMOV, AV
    ZHURNAL VSESOYUZNOGO KHIMICHESKOGO OBSHCHESTVA IMENI D I MENDELEEVA, 1984, 29 (04): : 467 - 468
  • [35] SIMPLE SYNTHESIS OF 3,3-BIS (TRIFLUOROMETHYL)-3H-1,2,4-DITHIAZOLES
    BURGER, K
    ALBANBAUER, J
    STRYCH, W
    SYNTHESIS-STUTTGART, 1975, (01): : 57 - 58
  • [36] Reactivity of (E)-1-(tert-butyldimethyl)silyloxy-3,3-bis(tributylstannyl)-propene: Syn selective S-E' addition to aldehydes
    Madec, D
    Ferezou, JP
    TETRAHEDRON LETTERS, 1997, 38 (38) : 6661 - 6664
  • [37] 3,3-BIS(DIFLUOROAMINO)BUTYRIC ACID AND ITS DERIVATIVES
    FOKIN, AV
    VORONKOV, AN
    TIMOFEENKO, IA
    KOSYREV, YM
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1975, 24 (06): : 1340 - 1342
  • [38] CONDENSATION KINETICS OF "3,3-BIS(CHLOROMETHYL)OXACYCLOBUTANE WITH ALDEHYDES
    NURIEVA, PK
    SIRAEVA, IN
    KANTOR, EA
    RAKHMANKULOV, DL
    REACTION KINETICS AND CATALYSIS LETTERS, 1979, 11 (03): : 259 - 264
  • [39] CRYSTALLIZATION OF POLY-[3,3-BIS(CHLOROMETHYL)OXACYCLOBUTANE]
    HATANO, M
    KAMBARA, S
    POLYMER, 1961, 2 (01) : 1 - 7
  • [40] 3,3-BIS(DIFLUOROAMINO)-BUTYRIC ACID AND ITS DERIVATIVES
    FOKIN, AV
    TIMOFEEN.IA
    VORONKOV, AN
    KOSYREV, YM
    IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1972, (05): : 1221 - &
12345