Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface

被引:14
|
作者
Shen, Ming-xue [1 ,2 ]
Zhang, Zhao-xiang [2 ,3 ]
Yang, Jin-tao [2 ]
Xiong, Guang-yao [1 ]
机构
[1] East China Jiaotong Univ, Coll Mat Sci & Engn, Nanchang 330013, Jiangxi, Peoples R China
[2] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310032, Zhejiang, Peoples R China
[3] Tsinghua Univ, State Key Lab Tribol, Beijing 100084, Peoples R China
基金
中国博士后科学基金; 美国国家科学基金会;
关键词
polymer brushes; textured surface; wettability; load-bearing capacity; friction reduction and anti-wear; SOLID LUBRICANT; FRICTION; PERFORMANCE; RESISTANCE;
D O I
10.3390/polym11060981
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polymer brush layers can act as effective lubricants owing to their low friction and good controllability. However, their application to the field of tribology is limited by their poor wear resistance. This study proposes a strategy combining grafting and surface texturing to extend the service life of polymer brushes. Surface microstructure and chemical composition were measured through scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). Water contact angles were measured to evaluate the surface wettability of the grafted silicon-based surface texture. Results showed the distinct synergistic effect between polymer brushes and laser surface texturing (LST). The prepared polymer brushes on textured surface can be a powerful mechanism for friction reduction properties, which benefit from their strong hydration effect on the lubrication liquid and promote the formation of a local lubricating film. Moreover, the wear life of polymer brushes can be immensely extended, as micro-dimples on the textured surface can effectively protect the polymer brushes. This study presents a method to enhance the load-bearing capacity and wear resistance of the grafted surface of polymer brushes.
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页数:16
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