Determination of molybdenum(VI) with phenylfluorone by diffuse reflection spectroscopy on a fibrous material filled with an anion exchanger

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作者
Shvoeva, OP [1 ]
Dedkova, VP [1 ]
Savvin, SB [1 ]
机构
[1] Russian Acad Sci, Vernadsky Inst Geochem & Analyt Chem, Moscow 117975, Russia
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O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Different systems consisting of a reagent and a fibrous adsorbent filled with an anion exchanger were studied for determining molybdenum(VI) by solid-phase spectroscopy. A system of a fibrous adsorbent filled with an AV-17 anion exchanger and phenylfluorone was selected and studied. The system provides the determination of molybdenum with a detection limit of 0.002 mg/L in the presence of different cations that usually interfere with the determination. A procedure for determining molybdenum (RSD < 15%) was developed and verified in analyses of river, well, and tap water. The analysis takes 15-20 min.
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页码:1006 / 1009
页数:4
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