Asymmetric cyclopropanation reaction under phase-transfer catalyzed conditions

被引：94
|
作者：
Arai, S [1 ]
Nakayama, K
Ishida, T
Shioiri, T
机构：
[1] Nagoya City Univ, Fac Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan
[2] Osaka Univ Pharmaceut Sci, Takatsuki, Osaka 5691041, Japan
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 22期
关键词：
asymmetric reactions; catalysts; cyclopropanes; phase transfer;
D O I：
10.1016/S0040-4039(99)00679-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An asymmetric cyclopropanation reaction was developed using chiral quaternary ammonium salts as the phase-transfer catalyst (PTC). The reaction smoothly proceeded to give the desired bicyclic compounds with complete stereocontrol in the presence of a catalytic amount of chiral quaternary salts as the PTC, which are derived from readily available chiral amines, with up to 83% ee under mild reaction conditions. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4215 / 4218
页数：4
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