First stereoselective total synthesis of panaxjapyne C

被引：5

作者：

Thakur, Pallavi ^{[1
]}

Kumaraswamy, B. ^{[1
]}

Reddy, G. Raji ^{[1
]}

Bandichhor, Rakeshwar ^{[2
]}

Mukkanti, K. ^{[3
]}

机构：

[1] Maithili Life Sci Pvt Ltd, IDA, Hyderabad 500076, Andhra Pradesh, India

[2] Dr Reddys Labs Ltd, R&D, IPD, Qutubullapur 500073, Andhra Pradesh, India

[3] JNT Univ, Ctr Environm Sci, Inst Sci & Technol, Hyderabad 500072, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2012年 / 53卷 / 29期

关键词：

Polyacetylene; Araliaceae; Regioselective opening of epoxide; Cadiot-Chodkiewicz cross coupling; L-ascorbic acid; OPLOPANAX; CHEMISTRY; ALKYNES;

D O I：

10.1016/j.tetlet.2012.04.087

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first stereoselective total synthesis of polyacetylene panaxjapyne C is described. The key reactions include regioselective opening of the epoxide and Cadiot-Chodkiewicz cross-coupling reactions. L-Ascorbic acid was used as a chiral pool material for the construction of the both terminal acetylenes. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：3703 / 3705

页数：3

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