Structural and optical properties of conjugated polymer and carbon-based non-fullerene material blend films for photovoltaic applications

被引:10
|
作者
Feng, Lin [1 ]
Wang, Fei [1 ]
Niu, Meng-Si [1 ]
Zheng, Fei [1 ]
Bi, Peng-Qing [1 ]
Yang, Xiao-Yu [1 ]
Xu, Wei-Long [1 ]
Hao, Xiao-Tao [1 ,2 ]
机构
[1] Shandong Univ, Sch Phys, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China
[2] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
来源
OPTICAL MATERIALS EXPRESS | 2017年 / 7卷 / 03期
基金
中国国家自然科学基金;
关键词
SOLAR-CELLS; THIN-FILMS; P3HT/PCBM; GRAPHENE; CAST;
D O I
10.1364/OME.7.000687
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, the structural and optical properties of bulk heterojunctions (BHJ) composed of MEH-PPV and carbon-based non-fullerene nanodiamond (ND) have been investigated. The steady-state absorption, temperature-dependent fluorescence and Raman spectroscopy demonstrate the conjugated length is increased and more ordered crystalline domains are formed in MEH-PPV films with the increment of ND content. The time-resolved fluorescence spectroscopy and 2D microscopy indicate that the BHJs with higher concentrations of ND may enhance the donor/acceptor interfacial contact which favors the dissociation of excitons into free charge carriers. Solar cells based on MEH-PPV:ND BHJs have been fabricated to explore the interplay between structural, photophysical properties, and ultimately, device performances. The results show that optimization of blend composition and structures with ND may improve the efficiency of the thin film photovoltaic devices. (C) 2017 Optical Society of America
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页码:687 / 697
页数:11
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