Crazing in two and three dimensions. 1. Two-dimensional crazing

被引:28
|
作者
Krupenkin, TN
Fredrickson, GH
机构
[1] AT&T Bell Labs, Lucent Technol, Murray Hill, NJ 07974 USA
[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/ma981014g
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A simple model is proposed to describe crazing in a very thin polymer film. It is argued that if the thickness of the film is below a certain critical value, the craze microstructure becomes similar to the deformation zone (two-dimensional neck) with the superimposed fibril structure. Deformation zone profile, characteristic fibril size, draw ratio, and critical film thickness are calculated as functions of material parameters and imposed strain rate. The results obtained are in good agreement with experimental values. The predictions of the model can also be used to verify the model of crazing in thick films and bulk polymers, which is described in Part 2 of the present series.
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页码:5029 / 5035
页数:7
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