Guest-tuned spin crossover in flexible supramolecular assemblies templated by a halide (Cl-, Br- or I-)

被引：18

作者：

Darawsheh, M. D. ^{[1
,2
]}

Barrios, L. A. ^{[1
,2
]}

Roubeau, O. ^{[3
,4
]}

Teat, S. J. ^{[5
]}

Aromi, G. ^{[1
,2
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, Diagonal 645, E-08028 Barcelona, Spain

[2] Univ Barcelona, IN2UB, Diagonal 645, E-08028 Barcelona, Spain

[3] CSIC, ICMA, Plaza San Francisco S-N, E-50009 Zaragoza, Spain

[4] Univ Zaragoza, Plaza San Francisco S-N, E-50009 Zaragoza, Spain

[5] Berkeley Lab, Adv Light Source, 1 Cyclotron Rd, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 03期

基金：

欧洲研究理事会;

关键词：

COORDINATION CHEMISTRY; MOLECULAR MACHINES; COMPLEXES; LIGHT;

D O I：

10.1039/c6cc08906b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligand 1,3-bis(3-(pyridin-2-yl)-1H-pyrazol-5-yl) benzene, L, forms mononuclear spin crossover complexes [FeL3](2+) with pendant arms that cause them to dimerize through numerous intermolecular interactions forming supramolecular (X@[FeL3](3+) cations. They have the flexibility to encapsulate Cl-, Br- or I-), which allow tuning the magnetic properties, in the solid state and in solution.

引用

页码：569 / 572

页数：4

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