STABILIZATION ENERGIES OF CL-, BR-, AND I- IONS IN WATER CLUSTERS

被引：113
|
作者：
PERERA, L
BERKOWITZ, ML
机构：
[1] Department of Chemistry, University of North Carolina, Chapel Hill
来源：
JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 05期
关键词：
D O I：
10.1063/1.466096
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Molecular dynamics computer simulations were performed on clusters of Cl- (H2O)n (n = 2,...,15). From the simulations we calculated the stabilization energies of the anion in the cluster. These energies were compared with the values of stabilization energies obtained from the photodetachment spectra of X-(H2O)n clusters (X = Cl-, Br-, or I-). The comparison confirms the hypothesis that the anion is attached to the water cluster.
引用
收藏
页码：4222 / 4224
页数：3
相关论文
共 50 条
  • [1] PHOTOELECTRON-SPECTROSCOPY OF CL-, BR-, AND I- SOLVATED IN WATER CLUSTERS
    MARKOVICH, G
    POLLACK, S
    GINIGER, R
    CHESHNOVSKY, O
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (11): : 9344 - 9353
  • [2] Cl- Br- I-的鉴定
    刘秀萍
    肖海光
    [J]. 晋中学院学报, 2000, (02) : 24 - 5
  • [3] MOBILITIES OF F-, CL-, BR-, AND I- IONS IN HE
    DOTAN, I
    ALBRITTON, DL
    FEHSENFELD, FC
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (05): : 2232 - 2233
  • [4] Complexes of antamanide with Cl-, Br- and I- anions
    Vanura, Petr
    Sykora, David
    Uhlikova, Tereza
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2024, 1309
  • [5] ENERGIES OF ELECTRONS DETACHED FROM NEGATIVE IONS I- BR- AND CL- IN COLLISIONS WITH INERT-GAS ATOMS
    BYDIN, YF
    [J]. JETP LETTERS-USSR, 1967, 6 (09): : 297 - &
  • [6] The solvation of Cl-, Br-, and I- in acetonitrile clusters: Photoelectron spectroscopy and molecular dynamics simulations
    Markovich, G
    Perera, L
    Berkowitz, ML
    Cheshnovsky, O
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (07): : 2675 - 2685
  • [7] COMPETITIVE ADSORPTION IN MONOLAYERS .5. CL-, BR- AND I- IONS ON SILVER AND ALUMINUM
    ARNIKAR, HJ
    DANIELS, EA
    KULKARNI, SV
    [J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1975, 52 (08) : 711 - 712
  • [8] INTERACTION OF PT SURFACES WITH AQUEOUS CL-, BR-, AND I- SOLUTIONS
    HUBBARD, AT
    BALTRUSCHAT, H
    FRANK, DG
    LU, F
    SCHARDT, BC
    STERN, DA
    STICKNEY, JL
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (03) : C127 - C127
  • [9] CL-, BR-, AND I- COLLISIONAL ELECTRON DETACHMENT RATE MEASUREMENTS
    MANDL, A
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (02): : 903 - 905
  • [10] SOLVATED POSITRON CHEMISTRY .2. REACTION OF HYDRATED POSITRONS WITH CL-,BR- AND I- IONS
    MOGENSEN, OE
    [J]. CHEMICAL PHYSICS, 1979, 37 (01) : 139 - 158
12345