Effects of Reaction Conditions on Methanol Produced to Dimethyl Ether

被引:0
|
作者
Liu, S. [1 ]
Zhang, L. [2 ]
机构
[1] Liaoning Shihua Univ, Fushun, Liaoning, Peoples R China
[2] SAIT Polytech, Calgary, AB T3G 3T7, Canada
关键词
dimethyl ether; effects; methanol; reaction conditions; Si-Al ratio;
D O I
10.1080/15567036.2012.654901
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Dimethyl ether can be obtained by using methanol as feedstock and MgO/HZSM-5 as catalysts. The effects of reaction conditions, such as loading of active components, weight hourly space velocity, reaction temperature, and Si-Al molar ratio, on methanol produced to dimethyl ether are mainly discussed. The experimental results indicate that it does not affect the skeleton structure of HZSM-5 molecular sieve too much with adding MgO; therefore, methanol's conversion reaches the maximum value when the weight hourly space velocity and the reaction temperature are 2 h(-1) and between 280 and 320 degrees C, respectively. For beta-zeolite and ZSM-5 zeolite, methanol's conversion increases with the increase of Si-Al molar ratio from 26 to 100 and from 30 to 80, respectively. The article aims to find the best conditions for methanol produced to dimethyl ether.
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页码:1937 / 1942
页数:6
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