Investigation of bio-oil produced by hydrothermal liquefaction of food waste using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry

被引:15
|
作者
Kostyukevich, Yury [1 ,2 ,3 ,4 ]
Vlaskin, Mikhail [4 ]
Borisova, Ludmila [5 ]
Zherebker, Alexander [6 ]
Perminova, Irina [6 ]
Kononikhin, Alexey [2 ,4 ]
Popov, Igor [2 ,3 ]
Nikolaev, Eugene [1 ,2 ,3 ]
机构
[1] Skolkovo Inst Sci & Technol, Novaya St 100, Skolkovo 143025, Russia
[2] Russian Acad Sci, Inst Energy Problems Chem Phys, Moscow, Russia
[3] Moscow Inst Phys & Technol, Moscow, Moscow Region, Russia
[4] Russian Acad Sci, Joint Inst High Temp, Moscow, Russia
[5] Natl Res Univ, Higher Sch Econ, Moscow, Russia
[6] Lomonosov Moscow State Univ, Dept Chem, Moscow, Russia
基金
俄罗斯科学基金会;
关键词
Bio-oil; food waste; electrospray; petroleomics; mass spectrometry; FT ICR; SOURCE HYDROGEN/DEUTERIUM EXCHANGE; ELECTROSPRAY-IONIZATION; H/D EXCHANGE; NITROGEN-COMPOUNDS; ORGANIC-MATTER; SPECTRA; MS; SPECIATION; CONVERSION; PYROLYSIS;
D O I
10.1177/1469066717737904
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Recent research has revealed that more than 1.3 billion tons of food is wasted globally every year. The disposal of such huge biomass has become a challenge. In the present paper, we report the production of the bio-oil by hydrothermal liquefaction of three classes of food waste: meat, cheese and fruits. The highest yield of the bio-oil was observed for meat (similar to 60%) and cheese (similar to 75%), while for fruits, it was considerably low (similar to 10%). The molecular composition of the obtained bio-oil was investigated using ultrahigh resolution Fourier Transform Ion Cyclotron Resonance mass spectrometry and was found to be similar to that obtained from algae. Several thousand heteroatom compounds (N, N-2, ON2, etc. classes) were reliably identified from each sample. It was found that bio-oils produced from meat and cheese have many compounds (similar to 90%) with common molecular formulas, while bio-oil produced from fruits differs considerably (similar to 30% of compounds are unique).
引用
收藏
页码:116 / 123
页数:8
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