A catalyst-free synthesis of asymmetric diaryl ketones from aryltins

被引：28

作者：

Silbestri, GF ^{[1
]}

Masson, RB ^{[1
]}

Lockhart, MT ^{[1
]}

Chopa, AB ^{[1
]}

机构：

[1] Univ Nacl Sur, Dept Quim, INIQO, RA-8000 Bahia Blanca, Argentina

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 08期

关键词：

aryltin; diarylketones; aromatic acylation;

D O I：

10.1016/j.jorganchem.2005.12.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of diaryl ketones have been synthesized in good yields (40-78%) through the catalyst-free reaction of trimethylarylstannanes with aroyl chlorides in chlorobenzene as solvent. In addition, all attractive feature is that these reactions are completely regioselective making possible the synthesis of diarylketones which are not usually available under the influence of the directing forces of the substituents present in the aromatic ring. Also, the reaction conditions are mild enough to be applied to acid sensitive molecules. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1520 / 1524

页数：5

共 50 条

[31] A SYNTHESIS OF DIARYL KETONES FROM ARYLMERCURIC SALTS
HECK, RF
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (20) : 5546 - &
[32] Green, Catalyst-Free Synthesis of Mesalazine Conjugates
Ibrahim, Mohamed A.
Panda, Siva S.
Alamry, Khalid A.
Katritzky, Alan R.
SYNTHESIS-STUTTGART, 2013, 45 (23): : 3255 - 3258
[33] Efficient and catalyst-free synthesis of cellulose acetoacetates
Hendryk Würfel
Marvin Kayser
Thomas Heinze
Cellulose, 2018, 25 : 4919 - 4928
[34] Ultrasound-Assisted Catalyst-free Synthesis of α,β-Unsaturated Amino Acid Esters and Unsaturated Amino Ketones
Xie, Guoshu
de Moura Ricketti, Nicolas
Torok, Bela
CURRENT GREEN CHEMISTRY, 2024, 11 (02) : 201 - 209
[35] Catalyst-free synthesis of α-acyloxycarboxamides in aqueous media
Daniel Paprocki
Monika Wilk
Arleta Madej
Peter Walde
Ryszard Ostaszewski
Environmental Chemistry Letters, 2019, 17 : 1011 - 1016
[36] Catalyst-free Solvothermal Synthesis of Carbon Nanotubes
Ellis, Tbomas
Paras, Christian
Stride, John A.
2008 INTERNATIONAL CONFERENCE ON NANOSCIENCE AND NANOTECHNOLOGY, 2008, : 40 - 43
[37] Catalyst-free facile and efficient one-pot synthesis of densely functionalized pyrroles and α-amino ketones
Vanga, Sivarama Krishna Reddy
Bollikolla, Hari Babu
Peruri, V. V. Satyanarayana
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2021, 58 (03) : 892 - 899
[38] Catalyst-Free Synthesis of Aminals from Indole-Derived ,-Dicyanoolefins
Cui, Hai-Lei
Shi, Yin
Deng, Hui-Qing
Lei, Jin-Ju
Xu, Xing-Jie
Tian, Xu
Qiao, Jie
Zhou, Lin
SYNLETT, 2019, 30 (02) : 167 - 172
[39] Catalyst-Free Dearomative Allylboration of Ketones with Benzo[b]thiophenylmethyl Boronic Acids
Liu, Kun
Ruan, Dao-Jin
Wang, Xiang-Yu
Zhong, Qin
Zhao, Jian Ken
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (18): : 13725 - 13729
[40] Chemoselective reduction of α,β-unsaturated ketones to allylic alcohols under catalyst-free conditions
Jian, Kaixia
Li, Bingnan
Zhu, Shuxian
Xuan, Qingqing
Song, Qiuling
ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (04): : 1109 - 1114

← 1 2 3 4 5 →