Metal ion-coupled electron-transfer reduction of dioxygen

被引：42

作者：

Fukuzumi, Shunichi ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

[2] Japan Sci & Technol Agcy, SORT, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY LETTERS | 2008年 / 37卷 / 08期

关键词：

D O I：

10.1246/cl.2008.808

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal ion-coupled and proton-coupled electron-transfer reactions of dioxygen is described for one-electron, two-electron, and four-electron reduction of dioxygen by one-electron reductants such as ferrocene derivatives as well as by two-electron reductants Such as NADH analogs. The catalytic mechanism of the four-electron reduction of dioxygen with cofacial dicobalt porphyrins has been clarified based on the detailed kinetic Study and the detection of the intermediate.

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页码：808 / 813

页数：6

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