Metal ion-coupled electron-transfer reduction of dioxygen

被引：42
|
作者：
Fukuzumi, Shunichi [1 ,2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
[2] Japan Sci & Technol Agcy, SORT, Suita, Osaka 5650871, Japan
来源：
CHEMISTRY LETTERS | 2008年 / 37卷 / 08期
关键词：
D O I：
10.1246/cl.2008.808
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal ion-coupled and proton-coupled electron-transfer reactions of dioxygen is described for one-electron, two-electron, and four-electron reduction of dioxygen by one-electron reductants such as ferrocene derivatives as well as by two-electron reductants Such as NADH analogs. The catalytic mechanism of the four-electron reduction of dioxygen with cofacial dicobalt porphyrins has been clarified based on the detailed kinetic Study and the detection of the intermediate.
引用
收藏
页码：808 / 813
页数：6
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