Frustrated Lewis Pair Mediated Hydrogenations

被引:91
|
作者
Stephan, Douglas W. [1 ]
Erker, Gerhard [2 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 1A1, Canada
[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
关键词
1,1-Disubstituted olefins; Aromatic reductions; Aziridines; Enamines; Enones; Enynes; Frustrated Lewis pairs; Heterolytic cleavage of dihydrogen; Hydrogenation catalysis; Imines; Nitriles; Silyl enol ethers; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; HOMOGENEOUS HYDROGENATION; ENANTIOSELECTIVE HYDROGENATION; POLYCYCLIC ARENES; BOND ACTIVATION; H-2; ACTIVATION; BORANES; IMINES; BIS(PENTAFLUOROPHENYL)BORANE;
D O I
10.1007/128_2012_392
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The development and use of frustrated Lewis pairs (FLPs) as both stoichiometric and catalytic reductants for the hydrogenation of a variety of organic substrate is described.
引用
收藏
页码:85 / 110
页数:26
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