Synthesis of N-(2,2,2-trichloro-1-hydroxyethyl)aldimines and their derivatives

被引：0
|
作者：
Firsova, Yu. N. [1 ]
Engel, S. R. [1 ]
Lozinskaya, N. A. [1 ]
Sosonyuk, S. E. [1 ]
Proskurnina, M. V. [1 ]
Zefirov, N. S. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 01期
关键词：
2,2,2-trichloro-1-(arylideneamino)ethanols; N-(2,2,2-trichloro-1-hydroxyethyl)aldimines; cyclopropenone; silylation; acylation; OXIDATION; ALDEHYDES; ESTERS;
D O I：
10.1007/s11172-015-0823-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preparative procedure for the synthesis of N-(2,2,2-trichloro-1-hydroxyethyl)aldimines from the corresponding aldehyde, chloral, and ammonium acetate was developed. Preparative silylation and acylation of their hydroxy groups were acomplished for the first time. The possibility to use the synthesized O-trimethylsilyl and O-acetyl derivatives as the synthetic equivalents of N-nonsubstituted imines in the reactions with cyclopropenone was investigated.
引用
收藏
页码：76 / 82
页数：7
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