Electrochemical and Photophysical Study in Solution and on Ruthenium(II) Polypyridyl Complexes Containing Thiophenylethynylphenanthrolines Self-assembled on Gold Surfaces

被引：2

作者：

Shiotsuka, Michito ^{[1
]}

Kondo, Hiroshi ^{[1
]}

Inomata, Tomohiko ^{[1
]}

Sako, Katsuya ^{[1
]}

Masuda, Hideki ^{[1
]}

机构：

[1] Nagoya Inst Technol, Grad Sch Engn, Showa Ku, Nagoya, Aichi 4668555, Japan

来源：

CHEMISTRY LETTERS | 2012年 / 41卷 / 11期

关键词：

TRANSITION-METAL-COMPLEXES; MOLECULAR JUNCTIONS; ELECTROGENERATED CHEMILUMINESCENCE; AROMATIC AMINATION; CHARGE-TRANSPORT; MONOLAYERS; ELECTRODE; CONDUCTANCE; WIRES; 2,2'-BIPYRIDINE;

D O I：

10.1246/cl.2012.1417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel ruthenium(II) polypyridyl complexes with diethynylphenanthrolines containing acetylthiophenyl unit(s) have been prepared and characterized by photophysical measurements. These complexes showed the MLCT and the lowest energy pi-pi* absorption bands, and also intensive broad emission bands assignable to a triplet MLCT transition were observed in the deaerated solution. The electrochemistry of these complexes in the solution and on self-assembled monolayers on the gold electrode clearly showed Ru(II)/R(III) redox waves.

引用

页码：1417 / 1419

页数：3

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