Mixed-Linker Hybrid Superpolyhedra for the Production of a Series of Large-Pore Iron(III) Carboxylate Metal-Organic Frameworks

被引：90

作者：

Chevreau, Hubert ^{[1
]}

Devic, Thomas ^{[1
]}

Salles, Fabrice ^{[2
]}

Maurin, Guillaume ^{[2
]}

Stock, Norbert ^{[3
]}

Serre, Christian ^{[1
]}

机构：

[1] Univ Versailles St Quentin En Yvelines, Inst Lavoisier, CNRS, UMR 8180, 45 Ave Etats Unis, F-78035 Versailles, France

[2] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, F-34095 Montpellier 05, France

[3] Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 19期

关键词：

carboxylate ligands; iron; mesoporous materials; metalorganic frameworks; microporous materials; SURFACE-AREA; COORDINATION COPOLYMER; ADSORPTION; TOPOLOGY; SITES; MOFS; DIFFRACTION; CLUSTERS; BEHAVIOR; SORPTION;

D O I：

10.1002/anie.201300057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It's all in the mix! Metal-organic frameworks (MOFs) were constructed from iron(III) trimers and mixtures of di- and tricarboxylate linkers. The dicarboxylate linker determined the size and shape of the pores in one series of materials with an interwoven structure and also enabled the introduction of different functionalities. Another mesoporous iron(III) MOF based on hybrid supertetrahedra had an extended β-cristobalite structure (see picture). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5056 / 5060

页数：5

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