Synthesis and crystal structure of 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin

被引：0
|
作者：
Bhyrappa, P [1 ]
Suslick, KS [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 1998年 / 2卷 / 4-5期
关键词：
tetraphenylporphyrin; tetraarylporphyrin; nitroporphyrin; synthesis; X-ray crystallography; structure determination;
D O I：
10.1002/(SICI)1099-1409(199807/10)2:4/5<391::AID-JPP95>3.3.CO;2-L
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis, characterization and crystal structure of the octanitro-substituted porphyrin 5,10,15,20-tetrakis(3,5-dinitrophenyl)porphyrin H2T(3,5-DNP)P, are described. The solid state structure has two porphyrins in the unit cell with eight pyridine solvates and is made up from columnar arrays of the porphyrins. X-ray crystal structure data: monoclinic, space group P1 2(1)/n1, a = 14.9996(9) Angstrom, b = 8.2489(5) Angstrom, c = 24.818(2) Angstrom, alpha = 90 degrees, beta = 104.172(1)degrees, gamma = 90 degrees, V = 2977.3(3) Angstrom(3), d(calc) = 1.440 g m(-3), Z = 2. (C) 1998 John Wiley & Sons, Ltd.
引用
收藏
页码：391 / 396
页数：6
相关论文
共 50 条
  • [31] Arrangement of a hydrophobically shielded porphyrin, 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin, in octadecylamine Langmuir-Blodgett multilayers
    Anikin, M
    Tkachenko, NV
    Lemmetyinen, H
    LANGMUIR, 1997, 13 (11) : 3002 - 3008
  • [32] Electrochemical Synthesis of Conducting Polyporphyrin Films based on 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin
    M. V. Tesakova
    V. I. Parfenyuk
    Surface Engineering and Applied Electrochemistry, 2021, 57 : 67 - 74
  • [33] 5,10,15,20-TETRAKIS(2-AMINO-6-METHOXYCARBONYLPHENYL)PORPHYRIN - SYNTHESIS AND SEPARATION OF ATROPISOMERS USEFUL FOR PORPHYRIN ARCHITECTURE
    NISHINO, N
    SAKAMOTO, T
    KIYOTA, H
    MIHARA, H
    YANAI, T
    FUJIMOTO, T
    CHEMISTRY LETTERS, 1993, (02) : 279 - 282
  • [34] STRUCTURE OF A NON-MESOGEN PORPHYRIN, 5,10,15,20-TETRAKIS[4-(1-HEXYLOXY)PHENYL]PORPHYRIN
    WALAWALKAR, MG
    NETHAJI, M
    KRISHNAN, V
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 479 - 481
  • [35] Clay catalyzed synthesis of 5,10,15,20-tetrakis (2,6-dichlorophenyl)-porphyrin and related porphyrins
    Chauhan, SMS
    Singh, R
    Gulati, A
    INDIAN JOURNAL OF HETEROCYCLIC CHEMISTRY, 2000, 9 (03) : 231 - 232
  • [36] Synthesis and characterization of some manganese complexes of 5,10,15,20-tetrakis (4-n-dodecylphenyl)porphyrin
    Hill, J
    Sugino, T
    Shimizu, Y
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 332 : 2629 - 2635
  • [37] Synthesis and Characterization of Some Manganese Complexes of 5,10,15,20-Tetrakis (4-n -Dodecylphenyl)Porphyrin
    Hill, Jonathan
    Sugino, Takushi
    Shimizu, Yo
    Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 332 : 119 - 125
  • [38] Electrochemical Synthesis of Conducting Polyporphyrin Films based on 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin
    Tesakova, M. V.
    Parfenyuk, V. I.
    SURFACE ENGINEERING AND APPLIED ELECTROCHEMISTRY, 2021, 57 (01) : 67 - 74
  • [39] Radiolysis of 5,10,15,20-tetrakis(N-methyl-4-pyridyl)-porphyrin or 5,10,15,20-tetrakis(4-sulfonatophenyl)-porphyrin in aqueous solution in the presence and in the absence of DNA or human serum albumin
    Strozik, Tadeusz
    Wolszczak, Marian
    Hilczer, Maria
    RADIATION PHYSICS AND CHEMISTRY, 2013, 91 : 156 - 165
  • [40] Synthesis and characterization of 5,10,15,20-Tetrakis[3-(3,4-dichlorophenoxy)]porphyrin and some of its metal complexes
    Tidwell, C. P.
    Bharara, P.
    Rudeseal, T. A.
    Rudeseal, G. M.
    Belmore, K.
    Bailey, M. J.
    Hubbard, J. T.
    HETEROCYCLIC COMMUNICATIONS, 2007, 13 (06) : 353 - 358
12345