Reactions induced in (CF3I) n clusters by femtosecond UV laser pulses

被引：12

作者：

Apatin, V. M. ^{[1
]}

Kompanets, V. O. ^{[1
]}

Lokhman, V. N. ^{[1
]}

Ogurok, N. -D. D. ^{[1
]}

Poydashev, D. G. ^{[1
,2
]}

Ryabov, E. A. ^{[1
]}

Chekalin, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Spect, Moscow 142190, Russia

[2] Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Oblast, Russia

来源：

JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS | 2012年 / 115卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

MULTIPHOTON IONIZATION; PHOTODISSOCIATION; STATES; SPECTROSCOPY; DYNAMICS; FIELD;

D O I：

10.1134/S106377611208002X

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The excitation and ionization of CF3I molecules and their clusters by femtosecond UV laser pulses is studied. It is concluded that the types of excitation of free CF3I molecules and their clusters by femtosecond UV laser pulses are different. The composition and kinetic energy of ion products observed upon the ionization of (CF3I) (n) clusters by femtosecond pulses are found to differ considerably from those obtained upon ionization by nanosecond pulses. It is shown that the molecular I (2) (+) ion is produced in reactions induced in (CF3I) (n) clusters by UV radiation. Using the pump-probe method, we found the two channels of producing I (2) (+) ions with characteristic times tau(1) a parts per thousand 1 ps and tau(2) a parts per thousand 7 ps. A model of the reactions under study proposed in the paper is consistent with our experimental results.

引用

页码：567 / 578

页数：12

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