Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane

被引：6

作者：

Spichal, Zdenek

Jancarik, Andrej

Mazal, Ctibor

Pinkas, Jiri

Pekarkova, Pavia

Necas, Marek ^{[1
]}

机构：

[1] Masaryk Univ, Fac Sci, Dept Chem, CS-61137 Brno, Czech Republic

来源：

POLYHEDRON | 2013年 / 62卷

关键词：

Bicyclopentanes; Lanthanides; Coordination polymers; X-ray crystallography; COMPLEXES; DIOXIDE;

D O I：

10.1016/j.poly.2013.06.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,3-bis(diphenylphosphoryl)bicyclo[1.1.1]pentane (1) with lanthanide nitrates provided a series of layered network coordination polymers Ln(1)(1.5)(NO3)(3) (Ln = Ce, Pr, Nd, Eu, Tb, Er, Yb, Lu). Crystal structures of all members of the series were determined by single crystal X-ray diffraction and were found isostructural. The compounds were studied by IR spectroscopy, luminescence spectroscopy, thermal analysis (TG/DSC) and powder X-ray diffraction (PXRD) techniques. (c) 2013 Elsevier Ltd. All rights reserved.

引用

页码：83 / 88

页数：6

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